3-Amino-N-methylbenzamide

Name: 3-Amino-N-methylbenzamide
Brand: ChemScene
Availability: InStock
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CAS No. 25900-61-2
Cat. No. CS-W019273
Purity≥97%
MDL No.MFCD00070630

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 25900-61-2

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General Information

CAS No. 25900-61-2
Cat. No. CS-W019273
Purity ≥97%
MDL No. MFCD00070630
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₁₀N₂O
Molecular Weight 150.18
Synonym(s) 3-Aminobenzoylmethylamide
SMILES O=C(NC)C1=CC=CC(N)=C1

Description

3-Amino-N-methylbenzamide features a strategically positioned amino group and methylated amide, enhancing solubility and metabolic stability. This combination enables direct incorporation into peptide scaffolds and bioactive molecules, offering improved membrane permeability and resistance to enzymatic degradation in medicinal chemistry applications.

Application

3-Amino-N-methylbenzamide serves as a versatile building block in medicinal chemistry, enabling direct access to substituted benzamide scaffolds through standard amide coupling and electrophilic substitution reactions. Its amino group facilitates derivatization via acylation, alkylation, or diazotization, while the N-methylated amide offers enhanced metabolic stability and favorable logP profiles. Bench-stable and readily purified by recrystallization, it functions effectively in multi-step syntheses of kinase inhibitors and other bioactive heterocycles.

Synthesis

Route1
- 3400-26-8
- ~99%
- In-stock
  
  25900-61-2
References
- Chen, Jian Jeffrey; Luk, Kin-Chun Thomas Patent: US2004/97493 A1, 2004 ; Location in patent: Page/Page column 24 ;
Route2
- In-stock
  
  99-05-8
- 74-89-5
- ~%
- In-stock
  
  25900-61-2
References
- Bulletin of the Korean Chemical Society, , vol. 32, # 12 p. 4444 - 4446

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS06
Signal Word : Danger	UN#: 2811
Class : 6.1	Packing Group : Ⅱ
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 55.12
LogP 0.6284
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Amino-N-methylbenzamide

CAS No. 25900-61-2

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