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CS-W001157 4
Total: USD 88.00

(Z)-But-2-ene-1,4-diyl diacetate

  • CAS No. 25260-60-0

  • Cat. No. CS-0197084
  • Purity≥95%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(Z)-But-2-ene-1,4-diyl diacetate|CS-0197084

Structure of 25260-60-0

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General Information

  • CAS No. 25260-60-0
  • Cat. No. CS-0197084
  • Purity ≥95%
  • MDL No. None
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₁₂O₄
  • Molecular Weight 172.18
  • Synonym(s) cis-2-Butene-1,4-diol Diacetate
  • SMILES CC(=O)OC/C=C\COC(=O)C

Description

cis-1,4-Diacetoxy-2-butene is an ester. Ruthenium olefin metathesis catalysts having cyclic (alkyl)(amino)carbenes effectively catalyzes the cross-metathesis of cis-1,4-diacetoxy-2-butene with allylbenzene. cis-1,4-Diacetoxy-2-butene on pyrolysis affords 1-acetoxy-1,3-butadiene, a diacetate and an isomeric 1,2-diacetoxy-3-butene. Mechanism of pyrolysis has been investigated.cis-1,4-Diacetoxy-2-butene may be used in the preparation of hindered Diels-Alder adducts. It may be used for the synthesis of 1,2,3,4-tetrahydro-2-vinylquinoxalines, via Palladium-catalyzed tandem allylation of 1,2-phenylenediamines.

Synthesis

  • Route1
    • In-stock
      cis-2-Butene-1,4-diol|CS-0071655
      6117-80-2
    • null|null
      108-24-7
    • ~98%
    • In-stock
      (Z)-But-2-ene-1,4-diyl diacetate|CS-0197084
      25260-60-0

    References

    • Brevet; Mori Synthesis, 1992 , # 10 p. 1007 - 1012
  • Route2
    • In-stock
      cis-2-Butene-1,4-diol|CS-0071655
      6117-80-2
    • null|null
      75-36-5
    • ~93%
    • In-stock
      (Z)-But-2-ene-1,4-diyl diacetate|CS-0197084
      25260-60-0

    References

    • Wang, Liang; Li, Pengfei; Menche, Dirk Angewandte Chemie - International Edition, 2010 , vol. 49, # 48 p. 9270 - 9273
  • Route3
    • null|null
      591-87-7
    • ~%
    • In-stock
      (Z)-But-2-ene-1,4-diyl diacetate|CS-0197084
      25260-60-0
    • (E)-But-2-ene-1,4-diyl diacetate|CS-0129877
      1576-98-3

    References

    • Journal of the American Chemical Society, , vol. 133, # 25 p. 9686 - 9688

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315
Precautionary Statements : P264-P280-P302+P352-P362+P364

Quality Control

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Computational Chemistry Data

  • TPSA   52.6
  • LogP   0.6688
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   4

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