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CS-W001157 4
Total: USD 88.00

4-(Carbomethoxy)aniline

  • CAS No. 619-45-4

  • Cat. No. CS-W009283
  • Purity≥98%
  • MDL No.MFCD00007891

*For research and further manufacturing use only, not for direct human use.

4-(Carbomethoxy)aniline|CS-W009283

Structure of 619-45-4

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General Information

  • CAS No. 619-45-4
  • Cat. No. CS-W009283
  • Purity ≥98%
  • MDL No. MFCD00007891
  • Storage 4°C, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₉NO₂
  • Molecular Weight 151.16
  • Synonym(s) Methyl 4-aminobenzoate
  • SMILES O=C(OC)C1=CC=C(N)C=C1

Description

The catalytic oxidation of methyl 4-aminobenzoate by hydrogen peroxide was studied.Methyl 4-aminobenzoate was used in the syntheses of guanidine alkaloids, ()-martinelline and ()-martinellic acid by a protic acid catalyzed hetero Diels-Alder coupling reaction with N-Cbz 2-pyrroline.

Synthesis

  • Route1

    References

    • Lee, Dae-Yon; Hartwig, John F. Organic Letters, 2005 , vol. 7, # 6 p. 1169 - 1172
  • Route2

    References

    • UNIVERSITY OF SOUTH FLORIDA; YALE UNIVERSITY Patent: WO2008/70823 A2, 2008 ; Location in patent: Page/Page column 5; 10-11; 9/14 ; WO 2008/070823 A2
  • Route3

    References

    • Lee, Dae-Yon; Hartwig, John F. Organic Letters, 2005 , vol. 7, # 6 p. 1169 - 1172

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   52.32
  • LogP   1.0554
  • H_Acceptors   3
  • H_Donors   1
  • Rotatable_Bonds   1

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