(R)-SPINOL

Name: (R)-SPINOL
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CAS No. 223259-62-9
Cat. No. CS-0031500
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 223259-62-9

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General Information

CAS No. 223259-62-9
Cat. No. CS-0031500
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₇H₁₆O₂
Molecular Weight 252.31
Synonym(s) (Ra)-1,1'-spirobiindane-7,7'-diol
SMILES OC1=CC=CC(CC2)=C1[C@]32C4=C(C=CC=C4O)CC3

Description

(R)-SPINOL is a chiral, bench-stable scaffold featuring a rigid, planar biaryl structure with strategically positioned hydroxyl groups. This configuration enables precise stereocontrol in asymmetric synthesis and serves as a robust ligand framework for transition metal catalysis.

Application

(R)-SPINOL serves as a privileged chiral scaffold in asymmetric synthesis, enabling enantioselective catalysis through its rigid, electron-rich biphenyl framework. Its stable, bench-ready structure facilitates straightforward handling and purification, while its orthogonal functional groups support diverse derivatization for catalyst development. Widely employed in organocatalytic transformations, it functions as a robust ligand platform for transition metal complexes and supports high enantiocontrol in C–C and C–heteroatom bond formation.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 40.46
LogP 3.2763
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 0

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(R)-SPINOL

CAS No. 223259-62-9

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