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CS-W001157 4
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(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonyl chloride

  • CAS No. 21286-54-4

  • Cat. No. CS-0020111
  • Purity≥97%
  • MDL No.MFCD00064156

*For research and further manufacturing use only, not for direct human use.

(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonyl chloride|CS-0020111

Structure of 21286-54-4

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General Information

  • CAS No. 21286-54-4
  • Cat. No. CS-0020111
  • Purity ≥97%
  • MDL No. MFCD00064156
  • Storage -20°C, sealed storage, away from moisture
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₅ClO₃S
  • Molecular Weight 250.74
  • Synonym(s) (+)-10-Camphorsulfonic acid chloride; (+)-10-Camphorsulfonyl chloride; (+)-Camphorsulfonyl chloride; (1S)-(+)-10-Camphorsulfonyl chloride; S-(+)-camphor-10-sulphoryl chloride
  • SMILES O=S(C[C@@]1(C2(C)C)C(C[C@@]2([H])CC1)=O)(Cl)=O

Synthesis

  • Route1

    References

    • Jung, Jae-Chul; Kache, Rajashaker; Vines, Kimberly K.; Zheng, Yan-Song; Bijoy, Panicker; Valluri, Muralikrishna; Avery, Mitchell A. Journal of Organic Chemistry, 2004 , vol. 69, # 26 p. 9269 - 9284
  • Route2
    • null|null
      77541-94-7
    • ~84%
    • In-stock
      (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonyl chloride|CS-0020111
      21286-54-4

    References

    • Namutebi, Mariam; McGarrigle, Eoghan M.; Aggarwal, Varinder K. Phosphorus, Sulfur and Silicon and the Related Elements, 2010 , vol. 185, # 5-6 p. 1250 - 1272
  • Route3

    References

    • Tetrahedron Letters, , vol. 54, # 32 p. 4247 - 4249

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 3261
Class : 8
Packing Group : Ⅲ
Hazard Statements : H314
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   51.21
  • LogP   1.9504
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   2

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