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CS-W001157 4
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[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]RuCl2

  • CAS No. 212210-87-2

  • Cat. No. CS-W020804
  • Purity≥98%
  • MDL No.MFCD02684566

*For research and further manufacturing use only, not for direct human use.

[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]RuCl2|CS-W020804

Structure of 212210-87-2

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General Information

  • CAS No. 212210-87-2
  • Cat. No. CS-W020804
  • Purity ≥98%
  • MDL No. MFCD02684566
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅₈H₄₈Cl₂N₂P₂Ru
  • Molecular Weight 1006.94
  • Synonym(s) dichlororuthenium, (1S,2S)-1,2-diphenylethane-1,2-diamine, [1-(2- diphenylphosphanyl-1-naphthyl)-2-naphthyl]-diphenyl-phosphane
  • SMILES Cl[Ru]12([P](C3=CC=CC=C3)(C4=CC=CC=C4)C(C=C5)=C(C6=C(C=CC=C7)C7=CC=C6[P](C8=CC=CC=C8)1C9=CC=CC=C9)C%10=C5C=CC=C%10)([NH2][C@@H](C%11=CC=CC=C%11)[C@H](C%12=CC=CC=C%12)[NH2]2)Cl

Description

This chiral ruthenium complex integrates a (R)-BINAP ligand and a (1S,2S)-DPEN co-ligand to deliver high enantioselectivity in asymmetric hydrogenation reactions. The bidentate phosphine-diamine architecture stabilizes the Ru(II) center, enabling efficient catalysis under mild conditions with excellent stereocontrol.

Safety Information

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GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Danger
UN#: 1325
Class : 4.1
Packing Group : Ⅱ
Hazard Statements : H228-H315-H319
Precautionary Statements : P210-P240-P241-P264-P280-P302+P352-P362+P364-P370+P378

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Computational Chemistry Data

  • TPSA   24.06
  • LogP   12.5943
  • H_Acceptors   2
  • H_Donors   2
  • Rotatable_Bonds   6

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