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CS-W001157 4
Total: USD 88.00

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

  • CAS No. 373650-12-5

  • Cat. No. CS-W020840
  • Purity≥98%
  • MDL No.MFCD09753024

*For research and further manufacturing use only, not for direct human use.

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)|CS-W020840

Structure of 373650-12-5

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General Information

  • CAS No. 373650-12-5
  • Cat. No. CS-W020840
  • Purity ≥98%
  • MDL No. MFCD09753024
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₄₂H₃₄O₈P₂Ru
  • Molecular Weight 829.73
  • Synonym(s) Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II),Ru(OAc)2[(S)-segphos]
  • SMILES CC1=O[Ru]23([P](C4=CC=CC=C4)(C5=CC=CC=C5)C6=[C@]([C@]7=C(OCO8)C8=CC=C7[P]2(C9=CC=CC=C9)C%10=CC=CC=C%10)C%11=C(OCO%11)C=C6)(OC(C)=O3)O1

Application

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) serves as a robust, bench-stable catalyst for asymmetric olefin metathesis and cross-coupling reactions. Its chiral bis(diphenylphosphino)benzodioxole ligand imparts high enantioselectivity in C–C bond formation, while the acetate ligands enable facile activation under mild conditions. The complex exhibits excellent functional group tolerance and is particularly effective in constructing stereodefined cyclic and acyclic olefins, making it a reliable tool for synthetic and medicinal chemistry workflows.

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   N/A
  • LogP   N/A
  • H_Acceptors   N/A
  • H_Donors   N/A
  • Rotatable_Bonds   N/A

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