4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine

Name: 4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine
Brand: ChemScene
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CAS No. 209901-86-0
Cat. No. CS-0160983
Purity≥98%
MDL No.MFCD06796986

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4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine|CS-0160983

Structure of 209901-86-0

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Description

4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine is a fluorinated terpyridine derivative featuring a para-fluorophenyl group conjugated to the central pyridine ring. This electron-deficient ligand integrates robust metal-chelating sites with enhanced solubility and stability under standard conditions. The fluorophenyl moiety improves electronic tuning and facilitates coordination in transition metal complexes for catalysis and materials applications.

Application

4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine serves as a versatile ligand scaffold in transition metal catalysis, enabling efficient coordination to late-stage metals such as Pd, Pt, and Ru. Its fluorinated aryl extension enhances electron-withdrawing character and improves solubility in organic media. The terpyridine core provides three nitrogen donor sites for robust chelation, facilitating catalyst design in cross-coupling and homogeneous catalysis. Bench-stable and readily purified by column chromatography, it functions effectively in standard synthetic workflows requiring modular ligand systems.

General Information

CAS No. 209901-86-0
Cat. No. CS-0160983
Purity ≥98%
MDL No. MFCD06796986
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₁H₁₄FN₃
Molecular Weight 327.36
Synonym(s) 4-(4-Fluorophenyl)-2,6-dipyridin-2-ylpyridine
SMILES FC1=CC=C(C=C1)C2=CC(=NC(=C2)C3=NC=CC=C3)C4=NC=CC=C4

Computational Chemistry Data

TPSA 38.67
LogP 5.0117
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 3

Safety Information

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GHS Pictogram : N/A	GHS No : N/A
Signal Word : N/A	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : N/A
Precautionary Statements : N/A

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Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Material Science Metal Organic Frameworks Nitrogen MOFs Linkers

Material Science Organic-Inorganic Hybrid Materials Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

Material Science Polymer/Macromolecule Reagents Metal Organic Frameworks (MOF) Raw Materials Organic Linker Molecules

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4'-(4-Fluorophenyl)-2,2':6',2''-terpyridine

CAS No. 209901-86-0

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