(9H-Fluoren-9-yl)methyl (4-aminophenyl)carbamate

Name: (9H-Fluoren-9-yl)methyl (4-aminophenyl)carbamate
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CAS No. 205688-13-7
Cat. No. CS-0155936
Purity≥96%
MDL No.MFCD12912141

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(9H-Fluoren-9-yl)methyl (4-aminophenyl)carbamate|CS-0155936

Structure of 205688-13-7

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General Information

CAS No. 205688-13-7
Cat. No. CS-0155936
Purity ≥96%
MDL No. MFCD12912141
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₁H₁₈N₂O₂
Molecular Weight 330.38
Synonym(s) N-(4-aminophenyl)-Carbamic acid9H-fluoren-9-ylmethyl ester
SMILES C1=CC=C2C(=C1)C3=CC=CC=C3C2COC(=O)NC4=CC=C(C=C4)N

Description

This fluorenylmethoxy carbamate derivative features a robust protecting group for primary amines, combining the stability of the 9-fluorenylmethyl (Fmoc) moiety with a para-aminophenyl linker. The carbamate linkage enables efficient deprotection under mild basic conditions, facilitating controlled release during peptide synthesis and enabling clean coupling reactions in biopharmaceutical workflows.

Application

(9H-Fluoren-9-yl)methyl (4-aminophenyl)carbamate serves as a robust amino-protecting group for peptide synthesis and nucleoside derivatization. Its fluorenylmethoxycarbonyl (Fmoc) moiety enables orthogonal deprotection under mild basic conditions, while the para-aminophenyl carbamate functionality offers enhanced stability and compatibility with diverse functional groups. This compound facilitates efficient solid-phase synthesis and simplifies purification through distinct chromatographic behavior.

Synthesis

Route1
- 941286-51-7
- ~%
- In-stock
  
  205688-13-7
References
- WO2009/37229 A1, ; Page/Page column 28 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362

Quality Control

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Computational Chemistry Data

TPSA 64.35
LogP 4.6298
H_Acceptors 3
H_Donors 2
Rotatable_Bonds 3

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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(9H-Fluoren-9-yl)methyl (4-aminophenyl)carbamate

CAS No. 205688-13-7

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