Lot numbers can be found on the outside label of a product:
1-Bromo-2,4-dimethoxybenzene
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CAS No. 17715-69-4
- Cat. No. CS-0008438
- Purity≥96%
- MDL No.MFCD00009844
*For research and further manufacturing use only, not for direct human use.
Structure of 17715-69-4
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General Information
- CAS No. 17715-69-4
- Cat. No. CS-0008438
- Purity ≥96%
- MDL No. MFCD00009844
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₈H₉BrO₂
- Molecular Weight 217.06
- Synonym(s) None
- SMILES COC1=CC=C(Br)C(OC)=C1
Description
1-Bromo-2,4-dimethoxybenzene was used in the synthesis of 2,3-disubstituted benzo[b]furans. It was also used in the synthesis of dendrimer Si[CH2CH2Si(Me)2-2,4-(MeO)2-C6H3]4.
Application
1-Bromo-2,4-dimethoxybenzene serves as a versatile building block in cross-coupling reactions, enabling efficient construction of substituted aromatic systems. The bromine moiety facilitates palladium-catalyzed coupling with boronic acids and organometallic reagents, while the ortho- and para-dimethoxy groups provide enhanced solubility and electronic modulation. Bench-stable and readily purified by column chromatography, it functions reliably in medicinal chemistry and materials synthesis workflows.
Synthesis
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Route1
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In-stock
151-10-0 - ~99%
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In-stock
17715-69-4
References
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Abusalim, Deyaa I.; Merfeld, Michelle L.; Lash, Timothy D. Journal of Organic Chemistry, 2013 , vol. 78, # 20 p. 10360 - 10368
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Route2
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In-stock
6626-15-9 -
74-88-4 - ~97%
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In-stock
17715-69-4
References
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PIERRE FABRE DERMO-COSMETIQUE; Poigny, Stéphane; Belaubre, Françoise Patent: US2014/50683 A1, 2014 ; Location in patent: Paragraph 0036 - 0038 ;
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References
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Tetrahedron Letters, , vol. 54, # 24 p. 3079 - 3081
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H315-H319-H335
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Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 18.46
- LogP 2.4663
- H_Acceptors 2
- H_Donors 0
- Rotatable_Bonds 2
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Key Words
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