(E)-Methyl 3-(3-aminophenyl)acrylate

Name: (E)-Methyl 3-(3-aminophenyl)acrylate
Brand: ChemScene
Availability: InStock
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CAS No. 163487-10-3
Cat. No. CS-0036729
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(E)-Methyl 3-(3-aminophenyl)acrylate|CS-0036729

Structure of 163487-10-3

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General Information

CAS No. 163487-10-3
Cat. No. CS-0036729
Purity ≥97%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₁NO₂
Molecular Weight 177.20
Synonym(s) methyl (E)-3-(3-aminophenyl)prop-2-enoate
SMILES COC(=O)/C=C/C1=CC(=CC=C1)N

Description

(E)-Methyl 3-(3-aminophenyl)acrylate features a conjugated acrylate system paired with a para-amino aromatic group, enabling efficient integration into diverse synthetic scaffolds. This electron-rich enone moiety facilitates nucleophilic additions and serves as a key building block in pharmaceutical and agrochemical synthesis. The methyl ester functionality supports further derivatization under standard conditions.

Application

(E)-Methyl 3-(3-aminophenyl)acrylate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted anilines and heterocyclic scaffolds. The conjugated enamide system exhibits robust stability under standard bench conditions and tolerates diverse functional groups, facilitating downstream transformations such as Suzuki-Miyaura coupling, electrophilic substitution, and cyclization reactions. Its amine functionality provides a direct handle for derivatization, while the ester group supports selective reduction or hydrolysis—making it particularly valuable in medicinal chemistry lead optimization and API precursor synthesis.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 52.32
LogP 1.455
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Olefins

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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(E)-Methyl 3-(3-aminophenyl)acrylate

CAS No. 163487-10-3

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