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CS-W001157 4
Total: USD 88.00

4,4',4'',4'''-Methanetetrayltetrabenzoic acid

  • CAS No. 160248-28-2

  • Cat. No. CS-0110614
  • Purity≥97%
  • MDL No.MFCD28385403

*For research and further manufacturing use only, not for direct human use.

4,4',4'',4'''-Methanetetrayltetrabenzoic acid|CS-0110614

Structure of 160248-28-2

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General Information

  • CAS No. 160248-28-2
  • Cat. No. CS-0110614
  • Purity ≥97%
  • MDL No. MFCD28385403
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₉H₂₀O₈
  • Molecular Weight 496.47
  • Synonym(s) 4-[Tris(4-carboxyphenyl)methyl]benzoic Acid
  • SMILES O=C(O)C1=CC=C(C=C1)C(C2=CC=C(C=C2)C(=O)O)(C3=CC=C(C=C3)C(=O)O)C4=CC=C(C=C4)C(=O)O

Description

This tetracarboxylic acid features a rigid methanetetrayl core that enforces precise spatial orientation of four benzoic acid units, enabling predictable multidentate coordination in supramolecular architectures. The structure resists conformational flexibility under standard conditions, facilitating controlled assembly in metal-organic frameworks and molecular recognition systems.

Application

4,4',4'',4'''-Methanetetrayltetrabenzoic acid serves as a rigid, tetracarboxylic scaffold for constructing highly ordered molecular architectures. Its four benzoic acid groups enable facile derivatization via amide or ester formation, while the methanetetrayl bridge provides structural rigidity and enhanced thermal stability. The molecule exhibits excellent bench stability and facilitates purification through crystallization, making it a practical building block for multi-functionalized systems in supramolecular chemistry and materials science applications.

Synthesis

  • Route1

    References

    • Grimm, Michael; Kirste, Burkhard; Kurreck, Harry Angewandte Chemie, 1986 , vol. 98, # 12 p. 1095 - 1099
  • Route2
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    • In-stock
      4,4',4'',4'''-Methanetetrayltetrabenzoic acid|CS-0110614
      160248-28-2

    References

    • Kirste, Burkhard; Grimm, Michael; Kurreck, Harry Journal of the American Chemical Society, 1989 , vol. 111, # 1 p. 108 - 114
  • Route3
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    • ~%
    • In-stock
      4,4',4'',4'''-Methanetetrayltetrabenzoic acid|CS-0110614
      160248-28-2

    References

    • Kirste, Burkhard; Grimm, Michael; Kurreck, Harry Journal of the American Chemical Society, 1989 , vol. 111, # 1 p. 108 - 114

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

Quality Control

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Computational Chemistry Data

  • TPSA   149.2
  • LogP   4.8621
  • H_Acceptors   4
  • H_Donors   4
  • Rotatable_Bonds   8

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