(R,R)-ANDEN-Phenyl Trost Ligand

Name: (R,R)-ANDEN-Phenyl Trost Ligand
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CAS No. 152140-65-3
Cat. No. CS-0093234
Purity≥97%
MDL No.MFCD12546007

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(R,R)-ANDEN-Phenyl Trost Ligand|CS-0093234

Structure of 152140-65-3

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General Information

CAS No. 152140-65-3
Cat. No. CS-0093234
Purity ≥97%
MDL No. MFCD12546007
Storage -20°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₅₄H₄₂N₂O₂P₂
Molecular Weight 812.87
Synonym(s) None
SMILES O=C(C1=C(P(C2=CC=CC=C2)C3=CC=CC=C3)C=CC=C1)N[C@@H]4[C@@H]5C(C=CC=C6)=C6[C@H]([C@H]4NC(C7=CC=CC=C7P(C8=CC=CC=C8)C9=CC=CC=C9)=O)C%10=C5C=CC=C%10

Description

This (R,R)-ANDEN-Phenyl Trost ligand delivers high enantioselectivity in palladium-catalyzed allylic alkylation reactions. Featuring a rigid chiral backbone and strategically positioned phenyl groups, it stabilizes transition states through defined steric and electronic interactions. The ligand exhibits excellent bench stability and compatibility with diverse nucleophiles, enabling efficient access to chiral building blocks under mild conditions.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 58.2
LogP 8.391
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 10

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(R,R)-ANDEN-Phenyl Trost Ligand

CAS No. 152140-65-3

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