tert-Butyl diallylcarbamate,98% (stabilized with MEHQ)

Name: tert-Butyl diallylcarbamate,98% (stabilized with MEHQ)
Brand: ChemScene
Availability: InStock
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CAS No. 151259-38-0
Cat. No. CS-0130879
Purity98% (stabilized with MEHQ)
MDL No.MFCD01321306

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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tert-Butyl diallylcarbamate,98% (stabilized with MEHQ)|CS-0130879

Structure of 151259-38-0

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General Information

CAS No. 151259-38-0
Cat. No. CS-0130879
Purity 98% (stabilized with MEHQ)
MDL No. MFCD01321306
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₁H₁₉NO₂
Molecular Weight 197.27
Synonym(s) tert-Butyl N,N-diallylcarbamate
SMILES O=C(OC(C)(C)C)N(CC=C)CC=C

Description

tert-Butyl diallylcarbamate, stabilized with MEHQ, features a robust tert-butyl carbamate handle ideal for selective protection in peptide synthesis. The diallyl functionality enables efficient coupling and orthogonal deprotection, while the stabilizing agent ensures shelf-life integrity under ambient conditions.

Application

tert-Butyl diallylcarbamate serves as a robust, bench-stable amine protecting group in peptide synthesis and medicinal chemistry. Its diallylcarbamate functionality enables orthogonal deprotection under mild hydrogenolysis conditions, while the tert-butyl moiety offers compatibility with acid-labile cleavage protocols. The stabilizer MEHQ prevents polymerization of the allyl groups during storage and handling, ensuring consistent reactivity and ease of purification in multi-step syntheses.

Synthesis

Route1
- In-stock
  
  24424-99-5
- 124-02-7
- ~10%
- In-stock
  
  151259-38-0
References
- ALBERT EINSTEIN COLLEGE OF YESHIVA UNIVERSITY; INDUSTRIAL RESEARCH LIMITED; EVANS, Gary Brian; LONGSHAW, Alistair Ian; SCHRAMM, Vern L.; TYLER, Peter, Charles Patent: WO2011/8110 A1, 2011 ; Location in patent: Page/Page column 41-42 ; WO 2011/008110 A1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 29.54
LogP 2.5955
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 4

Other Classifications

Building Blocks Functional Group Boc

Building Blocks Functional Group Olefins

Key Words

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tert-Butyl diallylcarbamate,98% (stabilized with MEHQ)

CAS No. 151259-38-0

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