[2,2'-Bipyridine]-4-carbaldehyde

Name: [2,2'-Bipyridine]-4-carbaldehyde
Brand: ChemScene
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CAS No. 146581-82-0
Cat. No. CS-0203077
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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[2,2'-Bipyridine]-4-carbaldehyde|CS-0203077

Structure of 146581-82-0

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General Information

CAS No. 146581-82-0
Cat. No. CS-0203077
Purity ≥97%
MDL No. None
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₁H₈N₂O
Molecular Weight 184.19
Synonym(s) 5-CHLOROMETHYL-6-OXAZOLIDINONE
SMILES O=CC1=CC=NC(C2=NC=CC=C2)=C1

Description

This bipyridine aldehyde features a reactive formyl group at the 4-position, enabling direct integration into coordination complexes and organic synthesis. The conjugated system enhances metal-chelation efficiency, while the bench-stable nature facilitates handling under standard conditions.

Application

[2,2'-Bipyridine]-4-carbaldehyde serves as a versatile building block for ligand synthesis, enabling efficient access to transition metal complexes via imine formation or oxidative coupling. Its aldehyde functionality exhibits excellent stability under standard bench conditions and tolerates diverse functional groups, facilitating straightforward purification and integration into catalytic systems. The molecule functions effectively in the construction of chelating ligands for homogeneous catalysis and coordination chemistry applications.

Synthesis

Route1
- In-stock
  
  56100-19-7
- ~36%
- In-stock
  
  146581-82-0
References
- Imperiali, Barbara; Prins, Thomas J.; Fisher, Stewart L. Journal of Organic Chemistry, 1993 , vol. 58, # 6 p. 1613 - 1616
Route2
- In-stock
  
  26482-00-8
- ~%
- In-stock
  
  146581-82-0
References
- Constable, Edwin C.; Figgemeier, Egbert; Housecraft, Catherine E.; Olsson, Jerry; Zimmermann, Yves C. Dalton Transactions, 2004 , # 13 p. 1918 - 1927

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P405-P501

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Computational Chemistry Data

TPSA 42.85
LogP 1.9561
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Key Words

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[2,2'-Bipyridine]-4-carbaldehyde

CAS No. 146581-82-0

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