(2S,2'S,3S,3'S)-Bis-BIDIME

Name: (2S,2'S,3S,3'S)-Bis-BIDIME
Brand: ChemScene
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CAS No. 1435940-21-8
Cat. No. CS-0088631
Purity≥95%
MDL No.MFCD31707598

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 1435940-21-8
Cat. No. CS-0088631
Purity ≥95%
MDL No. MFCD31707598
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₈H₄₄O₆P₂
Molecular Weight 658.70
Synonym(s) tert-butyl-4-(2,6-dimethoxyphenyl)-2,3-dihydro-1,3-benzoxaphosphol-2-yl]-4-(2,6-dimethoxyphenyl)-
SMILES [H][C@@]1([C@@]2([H])[P@](C(C)(C)C)C(C(C3=C(OC)C=CC=C3OC)=CC=C4)=C4O2)[P@@](C(C)(C)C)C5=C(C6=C(OC)C=CC=C6OC)C=CC=C5O1

Description

This chiral bis-bidentate ligand features two rigid, sterically defined imidazole-containing arms that enable precise metal coordination. Designed for asymmetric catalysis, it delivers high enantioselectivity in transition-metal-catalyzed transformations. The scaffold’s rigidity and defined stereochemistry enhance reproducibility and catalyst performance under standard conditions.

Application

(2S,2'S,3S,3'S)-Bis-BIDIME serves as a stereochemically defined chiral ligand scaffold for transition-metal catalysis, enabling asymmetric transformations in cross-coupling and hydrogenation reactions. Its rigid bis-bidentate architecture enhances enantioselectivity and catalyst stability, offering robust performance in synthetic workflows requiring high diastereoselectivity and operational simplicity.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 55.38
LogP 9.0036
H_Acceptors 6
H_Donors 0
Rotatable_Bonds 7

Key Words

(2S,2'S,3S,3'S)-Bis-BIDIME sigma(2S,2'S,3S,3'S)-Bis-BIDIME manufacturer(2S,2'S,3S,3'S)-Bis-BIDIME price(2S,2'S,3S,3'S)-Bis-BIDIME structure(2S,2'S,3S,3'S)-Bis-BIDIME SDSbuy (2S,2'S,3S,3'S)-Bis-BIDIME(2S,2'S,3S,3'S)-Bis-BIDIME supplier(2S,2'S,3S,3'S)-Bis-BIDIME uses(2S,2'S,3S,3'S)-Bis-BIDIME molecular weightprice of (2S,2'S,3S,3'S)-Bis-BIDIME(2S,2'S,3S,3'S)-Bis-BIDIME chemical name formula of (2S,2'S,3S,3'S)-Bis-BIDIME

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(2S,2'S,3S,3'S)-Bis-BIDIME

CAS No. 1435940-21-8

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