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CS-W001157 4
Total: USD 88.00

2,7-Dibromo-9H-fluoren-9-one

  • CAS No. 14348-75-5

  • Cat. No. CS-M3062
  • Purity≥97%
  • MDL No.MFCD00010790

*For research and further manufacturing use only, not for direct human use.

2,7-Dibromo-9H-fluoren-9-one|CS-M3062

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General Information

  • CAS No. 14348-75-5
  • Cat. No. CS-M3062
  • Purity ≥97%
  • MDL No. MFCD00010790
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₃H₆Br₂O
  • Molecular Weight 337.99
  • Synonym(s) 2,7-Dibromo-9-fluorenone; 2,7-Dibromo-9H-fluoren-9-one
  • SMILES O=C1C2=C(C3=C1C=C(Br)C=C3)C=CC(Br)=C2

Application

2,7-Dibromo-9H-fluoren-9-one serves as a versatile building block for brominated fluorenone scaffolds in organic synthesis. Its dibrominated structure enables efficient palladium-catalyzed cross-coupling reactions, while the ketone functionality offers sites for nucleophilic addition or enolate formation. The compound exhibits good bench stability and facilitates purification via recrystallization, making it suitable for applications in pharmaceutical intermediates and functional materials.

Synthesis

  • Route1

    References

    • Zhang, Xin; Han, Jun-Bin; Li, Peng-Fei; Ji, Xuan; Zhang, Zhao Synthetic Communications, 2009 , vol. 39, # 21 p. 3804 - 3815
  • Route2

    References

    • Zhang, Xin; Ji, Xuan; Jiang, Shanshan; Liu, Lili; Weeks, Brandon L.; Zhang, Zhao Green Chemistry, 2011 , vol. 13, # 7 p. 1891 - 1896
  • Route3

    References

    • Tetrahedron, , vol. 59, # 17 p. 3131 - 3156

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Computational Chemistry Data

  • TPSA   17.07
  • LogP   4.423
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   0

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