2-Bromo-4-iododibenzofuran

Name: 2-Bromo-4-iododibenzofuran
Brand: ChemScene
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CAS No. 1401068-25-4
Cat. No. CS-0619770
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 1401068-25-4
Cat. No. CS-0619770
Purity ≥97%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₆BrIO
Molecular Weight 372.98
Synonym(s) None
SMILES IC1=C2OC3=CC=CC=C3C2=CC(Br)=C1

Description

2-Bromo-4-iododibenzofuran features a sterically hindered dibenzofuran core with complementary halogen substituents, enabling selective cross-coupling reactions under palladium catalysis. The bromine and iodine positions facilitate sequential functionalization, while the planar aromatic system enhances stability and solubility in organic solvents. This compound serves as a key intermediate in the synthesis of conjugated materials for optoelectronic applications.

Application

2-Bromo-4-iododibenzofuran serves as a versatile building block for the synthesis of functionalized dibenzofuran scaffolds via palladium-catalyzed cross-coupling reactions. The orthogonal halogen reactivity enables sequential functionalization, with bromine typically participating in Suzuki or Stille couplings, while the iodine site undergoes efficient Negishi or Sonogashira transformations. Its bench-stable crystalline form and high purity facilitate reproducible, multi-step synthetic sequences in medicinal chemistry and materials science applications.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

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Computational Chemistry Data

TPSA 13.14
LogP 4.9531
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Oxygen compounds

Key Words

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2-Bromo-4-iododibenzofuran

CAS No. 1401068-25-4

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