2-Bromo-6-fluoro-4-methylbenzaldehyde

Name: 2-Bromo-6-fluoro-4-methylbenzaldehyde
Brand: ChemScene
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CAS No. 1370025-54-9
Cat. No. CS-0098740
Purity≥98%
MDL No.MFCD22056736

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Bromo-6-fluoro-4-methylbenzaldehyde|CS-0098740

Structure of 1370025-54-9

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General Information

CAS No. 1370025-54-9
Cat. No. CS-0098740
Purity ≥98%
MDL No. MFCD22056736
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₆BrFO
Molecular Weight 217.04
Synonym(s) None
SMILES O=CC1=C(C=C(C=C1Br)C)F

Description

2-Bromo-6-fluoro-4-methylbenzaldehyde features a trifunctional aromatic core with bromo, fluoro, and methyl groups positioned ortho to the aldehyde. This electron-deficient scaffold enables direct coupling in cross-coupling reactions and serves as a key intermediate in pharmaceutical synthesis. The aldehyde functionality offers high reactivity for nucleophilic additions and condensations under mild conditions.

Application

2-Bromo-6-fluoro-4-methylbenzaldehyde serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient construction of substituted aromatic scaffolds. Its orthogonal halogenation pattern facilitates palladium-catalyzed cross-coupling reactions, while the aldehyde group supports nucleophilic additions and condensation processes. The compound exhibits excellent bench stability and is compatible with standard purification protocols, making it well-suited for multi-step synthetic sequences requiring functional group tolerance and predictable reactivity.

Synthesis

Route1
- 50-00-0
- In-stock
  
  18349-09-2
- ~36%
- In-stock
  
  1370025-54-9
References
- Yamakawa, Naoki; Suemasu, Shintaro; Okamoto, Yoshinari; Tanaka, Ken-Ichiro; Ishihara, Tomoaki; Asano, Teita; Miyata, Keishi; Otsuka, Masami; Mizushima, Tohru Journal of Medicinal Chemistry, 2012 , vol. 55, # 11 p. 5143 - 5150

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P261-P280-P304+P340-P405

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Computational Chemistry Data

TPSA 17.07
LogP 2.70912
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Aldehyde

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-6-fluoro-4-methylbenzaldehyde

CAS No. 1370025-54-9

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