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CS-W001157 4
Total: USD 88.00

(1,3-Dithian-2-yl)trimethylsilane

  • CAS No. 13411-42-2

  • Cat. No. CS-0130866
  • Purity≥96%
  • MDL No.MFCD00006655

*For research and further manufacturing use only, not for direct human use.

(1,3-Dithian-2-yl)trimethylsilane|CS-0130866

Structure of 13411-42-2

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General Information

  • CAS No. 13411-42-2
  • Cat. No. CS-0130866
  • Purity ≥96%
  • MDL No. MFCD00006655
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₁₆S₂Si
  • Molecular Weight 192.42
  • Synonym(s) 2-Trimethylsilyl-1,3-dithiane
  • SMILES C[Si](C1SCCCS1)(C)C

Description

2-(Trimethylsilyl)-1,3-dithiane participates in Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines. It undergoes novel diazo transfer reaction with tosyl azide in hexamethylphosphoramide-THF to yield 2-diazo-1,3-dithiane, which on decomposition yields formal carbene adducts. It is a versatile acyl anion equivalent.

Synthesis

  • Route1
    • In-stock
      1,3-Dithiane|CS-W001189
      505-23-7
    • null|null
      75-77-4
    • ~87%
    • In-stock
      (1,3-Dithian-2-yl)trimethylsilane|CS-0130866
      13411-42-2

    References

    • Porskamp, P. A. T. W.; Leij, M. van der; Lammerink, B. H. M.; Zwanenburg, B. Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 9 p. 400 - 404
  • Route2
    • null|null
      75-77-4
    • null|null
      36049-90-8
    • ~85%
    • In-stock
      (1,3-Dithian-2-yl)trimethylsilane|CS-0130866
      13411-42-2

    References

    • Page, Philip C. Bulman; van Niel, Monique B.; Westwood, Donald Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 269 - 276
  • Route3
    • In-stock
      1,3-Dithiane|CS-W001189
      505-23-7
    • null|null
      65426-00-8
    • ~%
    • In-stock
      (1,3-Dithian-2-yl)trimethylsilane|CS-0130866
      13411-42-2
    • null|null
      97513-20-7

    References

    • Liebigs Annalen der Chemie, , # 5 p. 944 - 949

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07,GHS08,GHS09
Signal Word : Warning
UN#: 3082
Class : 9
Packing Group : Ⅲ
Hazard Statements : H332-H362-H372-H411
Precautionary Statements : P260-P261-P263-P264-P270-P271-P273-P304+P340-P391-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.06
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   1

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