tert-Butyl (4-(hydroxymethyl)bicyclo[2.2.2]octan-1-yl)carbamate

Name: tert-Butyl (4-(hydroxymethyl)bicyclo[2.2.2]octan-1-yl)carbamate
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CAS No. 1333384-43-2
Cat. No. CS-0091791
Purity≥97%
MDL No.MFCD27996090

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tert-Butyl (4-(hydroxymethyl)bicyclo[2.2.2]octan-1-yl)carbamate|CS-0091791

Structure of 1333384-43-2

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General Information

CAS No. 1333384-43-2
Cat. No. CS-0091791
Purity ≥97%
MDL No. MFCD27996090
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₄H₂₅NO₃
Molecular Weight 255.35
Synonym(s) tert-butyl 4-(hydroxyMethyl)bicyclo[2.2.2]octan-1-ylcarbaMate
SMILES O=C(OC(C)(C)C)NC1(CC2)CCC2(CO)CC1

Description

tert-Butyl (4-(hydroxymethyl)bicyclo[2.2.2]octan-1-yl)carbamate features a rigid bicyclic scaffold that delivers stereochemical stability, enabling precise functionalization at the hydroxymethyl position. The carbamate group offers convenient protection for amine intermediates, while the tertiary butyl moiety ensures excellent bench stability and compatibility with standard deprotection protocols.

Application

tert-Butyl (4-(hydroxymethyl)bicyclo[2.2.2]octan-1-yl)carbamate serves as a stable, bench-friendly building block for the synthesis of complex bicyclic scaffolds. The protected amine and pendant hydroxymethyl group enable orthogonal functionalization, facilitating downstream derivatization via oxidation, alkylation, or coupling reactions. Its rigid, sterically hindered framework enhances conformational control in target-oriented synthesis and supports efficient purification due to low polarity and high crystallinity.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P330-P501

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Computational Chemistry Data

TPSA 58.56
LogP 2.5964
H_Acceptors 3
H_Donors 2
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Functional Group Alcohol

Building Blocks Skeleton Bridge Rings compounds Quinine Ring compounds

Key Words

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tert-Butyl (4-(hydroxymethyl)bicyclo[2.2.2]octan-1-yl)carbamate

CAS No. 1333384-43-2

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