(4S)-1-Boc-4-amino-D-proline

Name: (4S)-1-Boc-4-amino-D-proline
Brand: ChemScene
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CAS No. 132622-78-7
Cat. No. CS-0028232
Purity≥95%
MDL No.MFCD08704543

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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General Information

CAS No. 132622-78-7
Cat. No. CS-0028232
Purity ≥95%
MDL No. MFCD08704543
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₁₈N₂O₄
Molecular Weight 230.26
Synonym(s) None
SMILES O=C(N1[C@@H](C(O)=O)C[C@H](N)C1)OC(C)(C)C

Description

(4S)-1-Boc-4-amino-D-proline is a stereochemically defined, bench-stable D-proline derivative featuring a Boc-protected amine at the C4 position. This configuration enables direct incorporation into peptide chains with precise stereocontrol, facilitating the synthesis of constrained peptidomimetics and bioactive oligomers under standard coupling conditions.

Application

(4S)-1-Boc-4-amino-D-proline serves as a stereochemically defined building block for the synthesis of D-proline-containing peptides and heterocyclic scaffolds. The Boc group provides orthogonal protection for the amine, enabling selective functionalization under standard coupling conditions. Its stability facilitates purification and handling, while the constrained pyrrolidine ring supports conformational rigidity in bioactive peptide analogs.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501

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Computational Chemistry Data

TPSA 92.86
LogP 0.4077
H_Acceptors 4
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Life Science Amino Acids and their Derivatives Proline and derivatives

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Chemical Biology Peptide Chemistry Amine Protection

Chemical Biology Peptide Chemistry Unnatural Amino Acid Derivatives

Key Words

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(4S)-1-Boc-4-amino-D-proline

CAS No. 132622-78-7

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