tert-Butyl (4-oxo-1,2,3,4-tetrahydronaphthalen-1-yl)carbamate

Name: tert-Butyl (4-oxo-1,2,3,4-tetrahydronaphthalen-1-yl)carbamate
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CAS No. 1313021-93-0
Cat. No. CS-0154404
Molecule weight261.32
Purity≥98%
MDL No.MFCD19689457

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tert-Butyl (4-oxo-1,2,3,4-tetrahydronaphthalen-1-yl)carbamate|CS-0154404

Structure of 1313021-93-0

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General Information

CAS No. 1313021-93-0
Cat. No. CS-0154404
Purity ≥98%
MDL No. MFCD19689457
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₅H₁₉NO₃
Molecular Weight 261.32
Synonym(s) N-(1,2,3,4-tetrahydro-4-oxo-1-naphthalenyl)Carbamic acid 1,1-dimethylethyl ester
SMILES CC(C)(OC(NC1CCC(C2=CC=CC=C21)=O)=O)C

Description

tert-Butyl (4-oxo-1,2,3,4-tetrahydronaphthalen-1-yl)carbamate delivers a protected hydroxyl-bearing naphthalene scaffold with enhanced stability and solubility. The carbamate group enables facile deprotection under mild acidic conditions, while the tetrahydronaphthalene core provides rigidity and lipophilic character. This compound serves as a key intermediate in the synthesis of bioactive molecules and complex natural product analogs.

Application

tert-Butyl (4-oxo-1,2,3,4-tetrahydronaphthalen-1-yl)carbamate serves as a stable, bench-ready protecting group for amines tethered to a tetralin core. It facilitates efficient late-stage functionalization in medicinal chemistry due to its compatibility with standard deprotection conditions and tolerance of diverse reaction environments. The carbamate moiety enables selective transformations while preserving the ketone functionality, supporting modular synthesis of complex heterocyclic scaffolds and API intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319
Precautionary Statements : P261-P302+P352

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Computational Chemistry Data

TPSA 55.4
LogP 3.2289
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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tert-Butyl (4-oxo-1,2,3,4-tetrahydronaphthalen-1-yl)carbamate

CAS No. 1313021-93-0

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