9-[2-(Diphenylphosphino)phenyl]-9H-carbazole

Name: 9-[2-(Diphenylphosphino)phenyl]-9H-carbazole
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CAS No. 1308652-67-6
Cat. No. CS-0087828
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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9-[2-(Diphenylphosphino)phenyl]-9H-carbazole|CS-0087828

Structure of 1308652-67-6

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Description

This carbazole derivative features a diphenylphosphino group at the 2-position, enabling robust coordination in palladium-catalyzed cross-coupling reactions. The electron-rich carbazole core enhances stability and facilitates efficient ligand integration in transition metal catalysis.

Application

9-[2-(Diphenylphosphino)phenyl]-9H-carbazole serves as a versatile, bench-stable phosphine ligand in palladium-catalyzed cross-coupling reactions. Its carbazole backbone provides steric and electronic modulation, while the ortho-diphenylphosphinoaryl group enables efficient coordination to transition metals. The ligand facilitates C–C and C–heteroatom bond formations under mild conditions, offering broad functional group tolerance and improved catalyst stability in Suzuki-Miyaura, Stille, and Negishi couplings.

General Information

CAS No. 1308652-67-6
Cat. No. CS-0087828
Purity ≥97%
MDL No. None
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₀H₂₂NP
Molecular Weight 427.48
Synonym(s) Ph PhenCar-Phos
SMILES C12=C(C=CC=C2)N(C3=C(P(C4=CC=CC=C4)C5=CC=CC=C5)C=CC=C3)C6=C1C=CC=C6

Computational Chemistry Data

TPSA 4.93
LogP 6.5419
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 4

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

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9-[2-(Diphenylphosphino)phenyl]-9H-carbazole

CAS No. 1308652-67-6

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