Lot numbers can be found on the outside label of a product:
Dimethyl 5-hydroxyisophthalate
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CAS No. 13036-02-7
- Cat. No. CS-W008167
- Purity≥98%
- MDL No.MFCD00134367
*For research and further manufacturing use only, not for direct human use.
Structure of 13036-02-7
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General Information
- CAS No. 13036-02-7
- Cat. No. CS-W008167
- Purity ≥98%
- MDL No. MFCD00134367
- Storage Store at room temperature
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₀H₁₀O₅
- Molecular Weight 210.18
- Synonym(s) Dimethyl 5-hydroxybenzene-1,3-dicarboxylate~5-Hydroxyisophthalic acid dimethyl ester
- SMILES O=C(OC)C1=CC(O)=CC(C(OC)=O)=C1
Description
Dimethyl 5-hydroxyisophthalate undergoes a base-catalyzed nucleophilic oxirane ring-opening addition reaction with allyl glycidyl ether, to afford 5-substituted derivatives of isophthalic acid. Influence of third component, i.e. a series of 1,-alkanediols on the copolymerization reaction of dimethyl 5-hydroxyisophthalate with poly(ethylene glycol) has been studied. Lipase-catalyzed condensation polymerization of dimethyl 5-hydroxyisophthalate with polyethylene glycol is reported.Novel building block derived from dimethyl 5-hydroxyisophthalate was used to prepare sterically crowded polyether dendrons, via O-allylation/Claisen rearrangement reactions. Dimethyl 5-hydroxyisophthalate may be used in the preparation of:bis(phebox) derivative of the cyclophosphazene5-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}benzene-1,3-dicarboxylic acid dimethyl esterfullerene derivative bearing a triethylene glycol-type polar head group
Synthesis
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Route1
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67-56-1 -
In-stock
618-83-7 - ~99%
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In-stock
13036-02-7
References
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Wilson, Andrew J.; Hong, Jason; Fletcher, Steven; Hamilton, Andrew D. Organic and Biomolecular Chemistry, 2007 , vol. 5, # 2 p. 276 - 285
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Route2
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In-stock
618-83-7
- ~99%
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In-stock
13036-02-7
References
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CLARIANT INTERNATIONAL LTD Patent: WO2005/118562 A1, 2005 ; Location in patent: Page/Page column 8 ;
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Route3
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168619-21-4 - ~93%
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In-stock
13036-02-7
References
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Ohgiya, Tadaaki; Nishiyama, Shigeru Tetrahedron Letters, 2004 , vol. 45, # 33 p. 6317 - 6320
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H315-H319-H335
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Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 72.83
- LogP 0.9654
- H_Acceptors 5
- H_Donors 1
- Rotatable_Bonds 2
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