Fmoc-3,4-dichloro-L-homophenylalanine

Name: Fmoc-3,4-dichloro-L-homophenylalanine
Brand: ChemScene
Availability: InStock
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CAS No. 1260616-12-3
Cat. No. CS-0188070
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Fmoc-3,4-dichloro-L-homophenylalanine|CS-0188070

Structure of 1260616-12-3

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General Information

CAS No. 1260616-12-3
Cat. No. CS-0188070
Purity ≥95%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₂₅H₂₁Cl₂NO₄
Molecular Weight 470.34
Synonym(s) Fmoc-L-HomoPhe(3,4-dichloro)-OH
SMILES C(OC(N[C@@H](CCC1=CC(Cl)=C(Cl)C=C1)C(O)=O)=O)C2C=3C(C=4C2=CC=CC4)=CC=CC3

Description

Fmoc-3,4-dichloro-L-homophenylalanine features a dichlorinated aromatic ring that enhances electron deficiency and steric bulk, enabling precise incorporation into peptide sequences. This derivative supports the synthesis of bioactive peptides with improved metabolic stability and membrane permeability under standard coupling conditions.

Application

Fmoc-3,4-dichloro-L-homophenylalanine serves as a valuable building block in peptide synthesis, enabling the incorporation of ortho-dichlorinated aromatic side chains. The Fmoc group facilitates efficient solid-phase peptide synthesis with orthogonal deprotection, while the dichlorophenyl moiety imparts enhanced metabolic stability and modulates electronic properties. This derivative exhibits excellent bench stability, compatibility with standard coupling conditions, and is readily purified by flash chromatography.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P302+P352

Quality Control

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Computational Chemistry Data

TPSA 75.63
LogP 5.9179
H_Acceptors 3
H_Donors 2
Rotatable_Bonds 7

Other Classifications

Building Blocks Functional Group Fmoc

Building Blocks Functional Group Chloride

Building Blocks Skeleton Chiral compounds Chiral Building Blocks

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Chemical Biology Peptide Chemistry Amine Protection

Chemical Biology Peptide Chemistry Unnatural Amino Acid Derivatives

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Fmoc-3,4-dichloro-L-homophenylalanine

CAS No. 1260616-12-3

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