6-Amino-3-bromo-2-methylbenzoic acid

Name: 6-Amino-3-bromo-2-methylbenzoic acid
Brand: ChemScene
Availability: InStock
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CAS No. 124341-06-6
Cat. No. CS-0146987
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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6-Amino-3-bromo-2-methylbenzoic acid|CS-0146987

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General Information

CAS No. 124341-06-6
Cat. No. CS-0146987
Purity ≥98%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO₂
Molecular Weight 230.06
Synonym(s) Benzoic acid, 6-amino-3-bromo-2-methyl-
SMILES O=C(O)C1=C(N)C=CC(Br)=C1C

Description

6-Amino-3-bromo-2-methylbenzoic acid features a strategically positioned amino group enabling direct functionalization, while the bromo and methyl substituents enhance regioselectivity in cross-coupling reactions. This electron-rich scaffold supports efficient derivatization under standard conditions.

Application

6-Amino-3-bromo-2-methylbenzoic acid serves as a versatile building block for the synthesis of functionalized aromatic scaffolds. The molecule enables direct derivatization at the amino and carboxylic acid groups, while the bromo and methyl substituents support palladium-catalyzed cross-coupling reactions and regioselective electrophilic substitutions. Its bench-stable nature and compatibility with standard purification protocols make it well-suited for medicinal chemistry campaigns and process development.

Synthesis

Route1
- 106976-22-1
- ~%
- In-stock
  
  124341-06-6
References
- Journal of Medicinal Chemistry, , vol. 33, # 2 p. 814 - 819
Route2
- In-stock
  
  76006-33-2
- ~%
- In-stock
  
  124341-06-6
References
- WO2013/177349 A2, ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 63.32
LogP 2.03792
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Carboxylic Acid

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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6-Amino-3-bromo-2-methylbenzoic acid

CAS No. 124341-06-6

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