1-(2-Amino-4-bromophenyl)ethanone

Name: 1-(2-Amino-4-bromophenyl)ethanone
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CAS No. 123858-51-5
Cat. No. CS-W006736
Purity≥95%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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1-(2-Amino-4-bromophenyl)ethanone|CS-W006736

Structure of 123858-51-5

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General Information

CAS No. 123858-51-5
Cat. No. CS-W006736
Purity ≥95%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO
Molecular Weight 214.06
Synonym(s) ethanone, 1-(2-amino-4-bromophenyl)-
SMILES CC(=O)C1=CC=C(Br)C=C1N

Description

1-(2-Amino-4-bromophenyl)ethanone features a brominated aromatic core paired with an amino group and acetyl functionality, enabling direct integration into pharmaceutical intermediates. This electron-rich scaffold supports diverse coupling reactions under mild conditions, delivering high yields in late-stage functionalization workflows.

Application

1-(2-Amino-4-bromophenyl)ethanone serves as a key intermediate in the synthesis of brominated aromatic amides and heterocyclic scaffolds. Its amino and bromo groups enable sequential functionalization via palladium-catalyzed cross-coupling and electrophilic substitution reactions. The acetophenone moiety provides a handle for oxidation, reduction, or enolization-based transformations, facilitating access to diverse pharmaceutical building blocks with high functional group tolerance and bench stability.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 43.09
LogP 2.2339
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ketone

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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1-(2-Amino-4-bromophenyl)ethanone

CAS No. 123858-51-5

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