Methyl 3-bromo-5-methylpicolinate

Name: Methyl 3-bromo-5-methylpicolinate
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CAS No. 1228880-68-9
Cat. No. CS-0153352
Purity≥97%
MDL No.MFCD12911847

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 3-bromo-5-methylpicolinate|CS-0153352

Structure of 1228880-68-9

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General Information

CAS No. 1228880-68-9
Cat. No. CS-0153352
Purity ≥97%
MDL No. MFCD12911847
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO₂
Molecular Weight 230.06
Synonym(s) Methyl 3-broMo-5-Methylpyridine-2-carboxylate
SMILES CC1=CC(=C(C(=O)OC)N=C1)Br

Description

Methyl 3-bromo-5-methylpicolinate is a bench-stable, electron-deficient heterocyclic ester featuring a bromine substituent at the 3-position and a methyl group at the 5-position of the picolinic acid core. This configuration enables direct functionalization in cross-coupling reactions, facilitating rapid access to substituted pyridine derivatives under mild conditions.

Application

Methyl 3-bromo-5-methylpicolinate serves as a versatile building block in synthetic organic chemistry, enabling palladium-catalyzed cross-coupling reactions due to its reactive bromo group. The methyl ester and methyl-substituted pyridine framework provide orthogonal functional handles for further derivatization, while the compound exhibits good bench stability and ease of purification—ideal for constructing heterocyclic scaffolds in medicinal chemistry and agrochemical research.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 1.93912
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 3-bromo-5-methylpicolinate

CAS No. 1228880-68-9

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