6-Bromo-7-methylquinoline

Name: 6-Bromo-7-methylquinoline
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 122759-89-1
Cat. No. CS-W007221
Purity≥98%
MDL No.MFCD18260428

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 122759-89-1

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General Information

CAS No. 122759-89-1
Cat. No. CS-W007221
Purity ≥98%
MDL No. MFCD18260428
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₈BrN
Molecular Weight 222.08
Synonym(s) None
SMILES CC1=C(Br)C=C2C=CC=NC2=C1

Description

6-Bromo-7-methylquinoline is a heterocyclic scaffold featuring bromine at the 6-position and a methyl group at the 7-position, enabling selective functionalization in cross-coupling reactions. This electron-deficient quinoline derivative exhibits enhanced solubility and stability under standard conditions, facilitating its use in medicinal chemistry and materials synthesis.

Application

6-Bromo-7-methylquinoline serves as a versatile building block in medicinal chemistry and catalytic synthesis, enabling direct functionalization at the C6 position via palladium-catalyzed cross-coupling. The methyl group at C7 enhances electron density, improving reactivity in electrophilic substitution and facilitating downstream derivatization. Its bench-stable nature and compatibility with standard reaction conditions make it ideal for constructing complex heterocyclic scaffolds in API development.

Synthesis

Route1
- In-stock
  
  6933-10-4
- In-stock
  
  56-81-5
- ~30%
- In-stock
  
  122759-89-1
References
- SGX PHARMACEUTICALS, INC. Patent: WO2008/51808 A2, 2008 ; Location in patent: Page/Page column 79-80 ; WO 2008/051808 A2

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 12.89
LogP 3.30572
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds quinoline compounds

Key Words

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6-Bromo-7-methylquinoline

CAS No. 122759-89-1

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