Methyl 5-bromo-6-chloropicolinate

Name: Methyl 5-bromo-6-chloropicolinate
Brand: ChemScene
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CAS No. 1214353-79-3
Cat. No. CS-0150755
Purity≥95%
MDL No.MFCD14698104

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Methyl 5-bromo-6-chloropicolinate|CS-0150755

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General Information

CAS No. 1214353-79-3
Cat. No. CS-0150755
Purity ≥95%
MDL No. MFCD14698104
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₅BrClNO₂
Molecular Weight 250.48
Synonym(s) Methyl 5-broMo-6-chloropyridine-2-carboxylate
SMILES COC(=O)C1=NC(=C(C=C1)Br)Cl

Description

Methyl 5-bromo-6-chloropicolinate is a halogenated pyridine derivative featuring strategically positioned bromo and chloro substituents at the 5- and 6-positions of the picolinate ring. This electron-deficient scaffold enables efficient coupling in cross-coupling reactions, offering enhanced reactivity for constructing complex heterocyclic architectures in medicinal chemistry and agrochemical synthesis.

Application

Methyl 5-bromo-6-chloropicolinate serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling selective functionalization at the C5 and C6 positions of the pyridine core. Its dual halogenation pattern facilitates palladium-catalyzed cross-coupling reactions, including Suzuki-Miyaura and Stille couplings, with excellent chemoselectivity. The methyl ester group provides a handle for subsequent derivatization, while the compound exhibits good bench stability and ease of purification, making it well-suited for iterative synthesis workflows.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 39.19
LogP 2.2841
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 5-bromo-6-chloropicolinate

CAS No. 1214353-79-3

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