(2-Chloro-5-formylphenyl)boronic acid

Name: (2-Chloro-5-formylphenyl)boronic acid
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CAS No. 1150114-78-5
Cat. No. CS-0042712
Molecule weight184.38
Purity≥96%
MDL No.MFCD06656269

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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(2-Chloro-5-formylphenyl)boronic acid|CS-0042712

Structure of 1150114-78-5

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General Information

CAS No. 1150114-78-5
Cat. No. CS-0042712
Purity ≥96%
MDL No. MFCD06656269
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BClO₃
Molecular Weight 184.38
Synonym(s) 2-Chloro-5-formylphenylboronic acid
SMILES OB(O)C1=C(Cl)C=CC(C=O)=C1

Description

This boronic acid features a chloro-substituted aromatic ring with a formyl group positioned ortho to the boronate moiety. The electrophilic formyl function enables direct coupling in Suzuki-Miyaura reactions, while the chlorine atom serves as a latent handle for downstream functionalization. Bench-stable and moisture-tolerant, it streamlines access to complex heterocycles and bioactive scaffolds in medicinal chemistry workflows.

Application

(2-Chloro-5-formylphenyl)boronic acid serves as a versatile building block in Suzuki-Miyaura coupling reactions, enabling the efficient construction of biaryl scaffolds under mild conditions. The formyl group provides orthogonal reactivity for downstream functionalization via oxime or hydrazone formation, while the boronic acid moiety offers excellent bench stability and compatibility with diverse reaction partners. Its dual functionality facilitates rapid access to complex molecular architectures common in medicinal chemistry and materials science.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 57.53
LogP -0.1677
H_Acceptors 3
H_Donors 2
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Boronic Acid And Its Ester

Building Blocks Functional Group Aldehyde

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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(2-Chloro-5-formylphenyl)boronic acid

CAS No. 1150114-78-5

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