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CS-W001157 4
Total: USD 88.00

Tris(trimethylsilyl) phosphate

  • CAS No. 10497-05-9

  • Cat. No. CS-0187713
  • Purity≥98%
  • MDL No.MFCD00008267

*For research and further manufacturing use only, not for direct human use.

Tris(trimethylsilyl) phosphate|CS-0187713

Structure of 10497-05-9

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General Information

  • CAS No. 10497-05-9
  • Cat. No. CS-0187713
  • Purity ≥98%
  • MDL No. MFCD00008267
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₂₇O₄PSi₃
  • Molecular Weight 314.54
  • Synonym(s) Phosphoricacidtrimethylsilylester
  • SMILES C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C

Description

Tris(trimethylsilyl) phosphate has been investigated as a novel film-forming additive for LiNi0.5Co0.2Mn0.3O2 cycling at high cut-off potential in LiPF6-based electrolyte. Tris(trimethylsilyl) phosphate [Tris(trimethylsilyl) ester of phosphoric acid] undergoes dealkylsilylation reaction with alumazene to yield heteroadamantane molecule.

Synthesis

  • Route1
    • null|null
      107-46-0
    • ~%
    • In-stock
      Tris(trimethylsilyl) phosphate|CS-0187713
      10497-05-9

    References

    • Zhurnal Obshchei Khimii, , vol. 25, p. 469; engl.Ausg.S. 437 Chemische Berichte, , vol. 90, p. 134 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 796
  • Route2
    • null|null
      999-97-3
    • ~92%
    • In-stock
      Tris(trimethylsilyl) phosphate|CS-0187713
      10497-05-9

    References

    • Journal of Organic Chemistry, , vol. 47, # 20 p. 3966 - 3969
  • Route3
    • null|null
      3385-94-2
    • ~82%
    • In-stock
      Tris(trimethylsilyl) phosphate|CS-0187713
      10497-05-9
    • null|null
      20152-28-7

    References

    • J. Gen. Chem. USSR (Engl. Transl.), , vol. 55, # 8 p. 1883 - 1884,1674 - 1675

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Danger
UN#: 1993
Class : 3
Packing Group : Ⅱ
Hazard Statements : H225-H315-H319-H335
Precautionary Statements : P210-P233-P240-P241-P242-P243-P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P370+P378-P405-P501

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Computational Chemistry Data

  • TPSA   44.76
  • LogP   4.649
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   6

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