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CS-W001157 4
Total: USD 88.00

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

  • CAS No. 104372-31-8

  • Cat. No. CS-W012975
  • Purity≥98%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine|CS-W012975

Structure of 104372-31-8

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General Information

  • CAS No. 104372-31-8
  • Cat. No. CS-W012975
  • Purity ≥98%
  • MDL No. None
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₁₅NO₃S
  • Molecular Weight 229.29
  • Synonym(s) 7,7-Dimethyl-1-[(Oxaziridin-2-Ylsulfonyl)Methyl]Bicyclo[2.2.1]Heptan-2-One; (1R)-(-)-(10-Camphorsulfonyl)oxaziridine
  • SMILES CC1(C)[C@](C2)(CC[C@@]1([H])C3)[C@]43N(O4)S2(=O)=O

Description

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine may be used as an oxidant to prepare (S)-(-)-vasicinone via asymmetric oxidation of deoxyvasicinone.

Synthesis

  • Route1
    • (3aR,6S)-8,8-Dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide|CS-0196492
      107869-45-4
    • ~%
    • In-stock
      (1R)-(-)-(10-Camphorsulfonyl)oxaziridine|CS-W012975
      104372-31-8

    References

    • Journal of the American Chemical Society, , vol. 110, p. 8477
  • Route2

    References

    • Journal of the American Chemical Society, , vol. 110, p. 8477
  • Route3
    • (1R)-10-Camphorsulfonamide|CS-W012947
      72597-34-3
    • ~%
    • In-stock
      (1R)-(-)-(10-Camphorsulfonyl)oxaziridine|CS-W012975
      104372-31-8

    References

    • Journal of the American Chemical Society, , vol. 110, p. 8477

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS03,GHS07
Signal Word : Danger
UN#: 1479
Class : 5.1
Packing Group : Ⅲ
Hazard Statements : H271-H315-H319-H335
Precautionary Statements : P210-P220-P280-P370+P378-P501

Quality Control

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Computational Chemistry Data

  • TPSA   49.68
  • LogP   1.0996
  • H_Acceptors   3
  • H_Donors   0
  • Rotatable_Bonds   0

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