Methyl 5-bromo-2-formylbenzoate

Name: Methyl 5-bromo-2-formylbenzoate
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 1016163-89-5
Cat. No. CS-0103320
Purity≥96%
MDL No.MFCD16036575

HazMat Fee +

HazMat Fee

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

The shipment is processed through FedEx Ground under the Limited Quantity option.

Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Methyl 5-bromo-2-formylbenzoate|CS-0103320

Structure of 1016163-89-5

Size

Price

Quantity

* Please select Quantity before adding items.

General Information

CAS No. 1016163-89-5
Cat. No. CS-0103320
Purity ≥96%
MDL No. MFCD16036575
Storage 4°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₇BrO₃
Molecular Weight 243.05
Synonym(s) None
SMILES O=C(C1=CC(Br)=CC=C1C=O)OC

Description

Methyl 5-bromo-2-formylbenzoate features a formyl group at the ortho position relative to the ester, creating a highly reactive electrophilic site. The para-bromo substitution enhances electron-withdrawing character, stabilizing adjacent intermediates in cross-coupling reactions. This compound integrates readily into complex molecular architectures under mild conditions, offering precise control in synthetic sequences requiring directed functionalization.

Application

Methyl 5-bromo-2-formylbenzoate serves as a versatile building block in synthetic organic chemistry, enabling direct functionalization at the formyl and bromo positions. Its ortho-formyl group facilitates nucleophilic addition and condensation reactions, while the bromine atom supports palladium-catalyzed cross-couplings. The methyl ester is compatible with standard reduction and derivatization protocols, offering a stable, bench-ready platform for constructing complex heterocycles and pharmaceutical intermediates.

Synthesis

Route1
- In-stock
  
  79670-17-0
- ~99%
- In-stock
  
  1016163-89-5
References
- Lartia, Remy; Allain, Clemence; Bordeau, Guillaume; Schmidt, Falk; Fiorini-Debuisschert, Celine; Charra, Fabrice; Teulade-Fichou, Marie-Paule Journal of Organic Chemistry, 2008 , vol. 73, # 5 p. 1732 - 1744
Route2
- In-stock
  
  4785-52-8
- 74-88-4
- ~%
- In-stock
  
  1016163-89-5
References
- Mirabdolbaghi, Roya; Dudding, Travis Tetrahedron, 2013 , vol. 69, # 15 p. 3287 - 3292
Route3
- 1265286-99-4
- ~95%
- In-stock
  
  1016163-89-5
References
- Herzog, Beat; Neier, Reinhard Arkivoc, 2011 , vol. 2011, # 6 p. 29 - 44

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P330-P501

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Computational Chemistry Data

TPSA 43.37
LogP 2.0482
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

Methyl 5-bromo-2-formylbenzoate sigmaMethyl 5-bromo-2-formylbenzoate manufacturerMethyl 5-bromo-2-formylbenzoate priceMethyl 5-bromo-2-formylbenzoate structureMethyl 5-bromo-2-formylbenzoate SDSbuy Methyl 5-bromo-2-formylbenzoateMethyl 5-bromo-2-formylbenzoate supplierMethyl 5-bromo-2-formylbenzoate usesMethyl 5-bromo-2-formylbenzoate molecular weightprice of Methyl 5-bromo-2-formylbenzoateMethyl 5-bromo-2-formylbenzoate chemical name formula of Methyl 5-bromo-2-formylbenzoate

Salutation:	*Country or Region:
*Applicant Name:	*Organization Name:
*Email Address:	Quantity:
CAS NO. :	Product Name:
Remarks:
Upload Pictures

CAS.No.		Product Name
Applicant Name *		Email Address *
Phone Number *		Organization Name*
Country or Region*		Quantity*
Remarks:

Product Name:
Cat. No.: .		CAS NO. :
Quantity:

Methyl 5-bromo-2-formylbenzoate

CAS No. 1016163-89-5

Recommended Products

General Information

Description

Application

Synthesis

References

References

References

Safety Information

Quality Control

Computational Chemistry Data

Similar Products

Other Classifications

Recently Viewed Products

Key Words