5-Bromo-6-fluoro-1H-benzo[d]imidazole

Name: 5-Bromo-6-fluoro-1H-benzo[d]imidazole
Brand: ChemScene
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CAS No. 1008360-84-6
Cat. No. CS-0042106
Purity≥98%
MDL No.MFCD11846341

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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5-Bromo-6-fluoro-1H-benzo[d]imidazole|CS-0042106

Structure of 1008360-84-6

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General Information

CAS No. 1008360-84-6
Cat. No. CS-0042106
Purity ≥98%
MDL No. MFCD11846341
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₄BrFN₂
Molecular Weight 215.02
Synonym(s) None
SMILES FC1=CC2=C(C=C1Br)N=CN2

Description

5-Bromo-6-fluoro-1H-benzo[d]imidazole features a fused bicyclic core with complementary halogen substituents enabling precise functionalization. The bromine and fluorine atoms provide orthogonal reactivity for cross-coupling and electrophilic substitution, facilitating integration into complex molecular architectures. This bench-stable heterocycle serves as a key building block in medicinal chemistry and materials science.

Application

5-Bromo-6-fluoro-1H-benzo[d]imidazole serves as a versatile heterocyclic building block in medicinal chemistry, enabling palladium-catalyzed cross-coupling reactions due to its orthogonal halogen reactivity. The bromo and fluoro substituents provide complementary handles for sequential functionalization, while the benzoimidazole core offers metabolic stability and favorable pharmacophoric properties. Bench-stable and compatible with standard synthetic workflows, it facilitates efficient construction of complex scaffolds in API development.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 28.68
LogP 2.4645
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Benzimidazole compounds

Key Words

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5-Bromo-6-fluoro-1H-benzo[d]imidazole

CAS No. 1008360-84-6

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