2-Bromo-6-methyl-4-nitropyridine

Name: 2-Bromo-6-methyl-4-nitropyridine
Brand: ChemScene
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CAS No. 97944-46-2
Cat. No. CS-0130292
Purity≥97%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2-Bromo-6-methyl-4-nitropyridine|CS-0130292

Structure of 97944-46-2

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General Information

CAS No. 97944-46-2
Cat. No. CS-0130292
Purity ≥97%
MDL No. None
Storage -20°C, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₅BrN₂O₂
Molecular Weight 217.02
Synonym(s) Pyridine,2-bromo-6-methyl-4-nitro
SMILES O=[N+]([O-])C1=CC(Br)=NC(C)=C1

Description

2-Bromo-6-methyl-4-nitropyridine is a halogenated pyridine derivative featuring a nitro group at C4 and a methyl substituent at C6. This electron-deficient heterocycle serves as a key intermediate in the synthesis of bioactive molecules, enabling efficient coupling reactions through its reactive bromine site. The compound exhibits good stability under standard bench conditions and facilitates modular construction in medicinal chemistry workflows.

Application

2-Bromo-6-methyl-4-nitropyridine serves as a versatile building block in heterocyclic synthesis, enabling palladium-catalyzed cross-coupling reactions due to its reactive bromide and electron-deficient pyridine core. The methyl and nitro groups provide orthogonal functional handles for further derivatization. Its bench-stable crystalline form facilitates handling and purification, making it well-suited for iterative synthesis of complex nitrogen-containing scaffolds in medicinal chemistry and materials science applications.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 56.03
LogP 2.06072
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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2-Bromo-6-methyl-4-nitropyridine

CAS No. 97944-46-2

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