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CS-W001157 4
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3,6-Dibromonaphthalene-2,7-diol

  • CAS No. 96965-79-6

  • Cat. No. CS-0157282
  • Purity≥97%
  • MDL No.MFCD00277643

*For research and further manufacturing use only, not for direct human use.

3,6-Dibromonaphthalene-2,7-diol|CS-0157282

Structure of 96965-79-6

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General Information

  • CAS No. 96965-79-6
  • Cat. No. CS-0157282
  • Purity ≥97%
  • MDL No. MFCD00277643
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₀H₆Br₂O₂
  • Molecular Weight 317.96
  • Synonym(s) 3,6-Dibromo-2,7-naphthalenediol
  • SMILES C1=C2C=C(C(=CC2=CC(=C1Br)O)O)Br

Description

Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.

Synthesis

  • Route1

    References

    • Tate, Daniel J.; Abdelbasit, Mohamed; Kilner, Colin A.; Shepherd, Helena J.; Warriner, Stuart L.; Bushby, Richard J. Tetrahedron, 2014 , vol. 70, # 1 p. 67 - 74
  • Route2
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      98994-89-9
    • ~85%
    • In-stock
      3,6-Dibromonaphthalene-2,7-diol|CS-0157282
      96965-79-6

    References

    • Takimiya, Kazuo Patent: US2011/224445 A1, 2011 ; Location in patent: Page/Page column 12 ;

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   40.46
  • LogP   3.776
  • H_Acceptors   2
  • H_Donors   2
  • Rotatable_Bonds   0

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