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CS-W001157 4
Total: USD 88.00

[(E)-2-(Benzenesulfonyl)ethenyl]sulfonylbenzene

  • CAS No. 963-16-6

  • Cat. No. CS-0035489
  • Molecule weight308.37
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

[(E)-2-(Benzenesulfonyl)ethenyl]sulfonylbenzene|CS-0035489

Structure of 963-16-6

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General Information

  • CAS No. 963-16-6
  • Cat. No. CS-0035489
  • Purity ≥97%
  • MDL No. None
  • Storage RT, protect from light
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₄H₁₂O₄S₂
  • Molecular Weight 308.37
  • Synonym(s) trans-1,2-Bis(phenylsulfonyl)ethylene
  • SMILES C1=CC=C(C=C1)S(=O)(=O)/C=C/S(=O)(=O)C2=CC=CC=C2

Description

Chiral BINAP-AuTFA- and chiral BINAP-AgTFA (TFA = trifluoroacetate anion) -promoted catalytic enantioselective 1,3-dipolar cycloadditions of iminoglycinates with trans-1,2-bis(phenylsulfonyl)ethylene were studied.trans-1,2-Bis(phenylsulfonyl)ethylene was used in total synthesis of (+)-7-deoxypancratistatin.

Synthesis

  • Route1

    References

    • Lucchi, Ottorino De; Lucchini, Vittorio; Pasquato, Lucia; Modena, Giorgio Journal of Organic Chemistry, 1984 , vol. 49, # 4 p. 596 - 604
  • Route2
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    • [(E)-2-(Benzenesulfonyl)ethenyl]sulfonylbenzene|CS-0035489
      963-16-6

    References

    • Journal of the American Chemical Society, , vol. 75, p. 1672 Journal of the American Chemical Society, , vol. 76, p. 5745 Journal of the American Chemical Society, , vol. 81, p. 4927,4929 Gazzetta Chimica Italiana, , vol. 86, p. 428,431, 755
  • Route3

    References

    • Reddy, D. Bhaskar; Babu, N. Chandrasekhar; Padmavathi; Sumathi Synthesis, 1999 , # 3 p. 491 - 494

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Computational Chemistry Data

  • TPSA   68.28
  • LogP   2.4054
  • H_Acceptors   4
  • H_Donors   0
  • Rotatable_Bonds   4

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