tert-Butyl (2-amino-3-methylphenyl)carbamate

Name: tert-Butyl (2-amino-3-methylphenyl)carbamate
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CAS No. 954238-92-7
Cat. No. CS-0153437
Molecule weight222.28
Purity≥97%
MDL No.MFCD09701247

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tert-Butyl (2-amino-3-methylphenyl)carbamate|CS-0153437

Structure of 954238-92-7

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General Information

CAS No. 954238-92-7
Cat. No. CS-0153437
Purity ≥97%
MDL No. MFCD09701247
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₂H₁₈N₂O₂
Molecular Weight 222.28
Synonym(s) (2-AMINO-3-METHYL-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER
SMILES CC1=C(N)C(NC(OC(C)(C)C)=O)=CC=C1

Description

tert-Butyl (2-amino-3-methylphenyl)carbamate features a protected ortho-aminoanisole scaffold, integrating a sterically hindered tert-butyl carbamate group with an electron-rich aromatic core. This stable, bench-ready derivative enables direct incorporation into peptide conjugation workflows and facilitates selective deprotection under mild acidic conditions.

Application

tert-Butyl (2-amino-3-methylphenyl)carbamate serves as a versatile orthogonally protected aniline building block, enabling efficient access to substituted benzene derivatives via mild acidolysis. The tert-butyl carbamate group provides excellent bench stability and facilitates purification, while the 2-amino-3-methyl substitution pattern supports diverse downstream transformations including palladium-catalyzed coupling reactions, electrophilic aromatic substitutions, and heterocycle construction in medicinal chemistry workflows.

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P362+P364

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Computational Chemistry Data

TPSA 64.35
LogP 2.92422
H_Acceptors 3
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amine

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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tert-Butyl (2-amino-3-methylphenyl)carbamate

CAS No. 954238-92-7

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