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CS-W001157 4
Total: USD 88.00

[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-yl idene][bis(trifluoromethanesulfonyl)imide]gold(I)

  • CAS No. 951776-24-2

  • Cat. No. CS-0111093
  • Purity≥97%
  • MDL No.None

*For research and further manufacturing use only, not for direct human use.

[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-yl idene][bis(trifluoromethanesulfonyl)imide]gold(I)|CS-0111093

Structure of 951776-24-2

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General Information

  • CAS No. 951776-24-2
  • Cat. No. CS-0111093
  • Purity ≥97%
  • MDL No. None
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₉H₃₆AuF₆N₃O₄S₂
  • Molecular Weight 865.70
  • Synonym(s) Iprauntf2
  • SMILES CC(C)C(C=CC=C1C(C)C)=C1N2C=CN(C3=C(C(C)C)C=CC=C3C(C)C)C2[Au]N(S(=O)(C(F)(F)F)=O)SOOC(F)(F)F

Application

[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-yl idene][bis(trifluoromethanesulfonyl)imide]gold(I) serves as a robust, bench-stable N-heterocyclic carbene gold(I) catalyst that facilitates a wide range of synthetically valuable transformations, including alkyne hydrofunctionalizations and cyclizations. Its steric bulk enhances catalyst longevity and selectivity in complex molecule assembly, while the triflimide counterion ensures high solubility and reactivity in polar and nonpolar media.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501

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Computational Chemistry Data

  • TPSA   62.32
  • LogP   9.4419
  • H_Acceptors   7
  • H_Donors   0
  • Rotatable_Bonds   12

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