3-Chloro-4-methylaniline

Name: 3-Chloro-4-methylaniline
Brand: ChemScene
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CAS No. 95-74-9
Cat. No. CS-M1324
Purity≥95%
MDL No.MFCD00007773

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Description

2-Chloro-4-aminotoluene has been used in the preparation of 2-chloro-4-cyanotoluene by Sandmeyer reaction with cuprous cyanide.

Application

3-Chloro-4-methylaniline serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling efficient construction of substituted anilines via standard coupling reactions. Its ortho-chloro and meta-methyl substituents provide favorable electronic and steric profiles for palladium-catalyzed cross-couplings, while the primary amine facilitates direct derivatization. Bench-stable and readily purified by distillation or recrystallization, it functions reliably in multi-step syntheses requiring functional group tolerance and predictable reactivity.

General Information

CAS No. 95-74-9
Cat. No. CS-M1324
Purity ≥95%
MDL No. MFCD00007773
Storage RT, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₈ClN
Molecular Weight 141.60
Synonym(s) 4-Amino-2-chlorotoluene
SMILES ClC1=CC(N)=CC=C1C

Computational Chemistry Data

TPSA 26.02
LogP 2.23062
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Safety Information

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GHS Pictogram :	GHS No : GHS06,GHS09
Signal Word : Danger	UN#: 2239
Class : 6.1	Packing Group : Ⅲ
Hazard Statements : H301+H311-H315-H319-H410
Precautionary Statements : P264-P270-P273-P280-P302+P352-P305+P351+P338-P330-P361+P364-P362+P364-P391-P405-P501

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Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Chloro-4-methylaniline

CAS No. 95-74-9

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