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CS-W001157 4
Total: USD 88.00

((Vinyloxy)methyl)benzene

  • CAS No. 935-04-6

  • Cat. No. CS-0049793
  • Purity≥96%
  • MDL No.MFCD12547209

*For research and further manufacturing use only, not for direct human use.

((Vinyloxy)methyl)benzene|CS-0049793

Structure of 935-04-6

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General Information

  • CAS No. 935-04-6
  • Cat. No. CS-0049793
  • Purity ≥96%
  • MDL No. MFCD12547209
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₀O
  • Molecular Weight 134.18
  • Synonym(s) Vinyloxymethyl-benzene
  • SMILES C=COCC1=CC=CC=C1

Description

This vinyloxy-containing aromatic compound integrates a reactive vinyl ether functionality adjacent to a benzene ring, enabling efficient incorporation into polymer architectures and cross-linking systems. The pendant vinyloxy group facilitates controlled radical addition and click-type transformations under mild conditions.

Application

(Vinyloxy)methyl)benzene serves as a versatile building block in synthetic organic chemistry, enabling efficient access to functionalized aromatic systems through electrophilic and radical-mediated transformations. Its vinyloxy-methyl moiety exhibits robust bench stability and compatibility with common reaction conditions, facilitating selective functionalization at the benzylic position. This compound functions effectively in palladium-catalyzed coupling reactions and serves as a precursor for heterocyclic scaffolds via cyclization protocols.

Synthesis

  • Route1
    • null|null
      108-05-4
    • In-stock
      Benzyl alcohol|CS-4355
      100-51-6
    • ~95%
    • In-stock
      ((Vinyloxy)methyl)benzene|CS-0049793
      935-04-6

    References

    • Okimoto, Yoshio; Sakaguchi, Satoshi; Ishii, Yasutaka Journal of the American Chemical Society, 2002 , vol. 124, # 8 p. 1590 - 1591
  • Route2
    • null|null
      60633-79-6
    • ~91%
    • In-stock
      ((Vinyloxy)methyl)benzene|CS-0049793
      935-04-6
    • null|null
      135983-64-1

    References

    • Ding, Bangwei; Bentrude, Wesley G. Journal of the American Chemical Society, 2003 , vol. 125, # 11 p. 3248 - 3259
  • Route3

    References

    • Grobelny, Zbigniew; Stolarzewicz, Andrzej; Maercker, Adalbert; Krompiec, Stanis; Kasperczyk, Janusz; Rzepa, Jozef; Frey, Holger Journal of Organometallic Chemistry, 2004 , vol. 689, # 14 p. 2361 - 2367

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02,GHS07
Signal Word : Danger
UN#: 1993
Class : 3
Packing Group : Ⅲ
Hazard Statements : H225-H315-H319
Precautionary Statements : P210-P233-P240-P241-P242-P243-P264-P280-P362+P364-P370+P378-P501

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Computational Chemistry Data

  • TPSA   9.23
  • LogP   2.3467
  • H_Acceptors   1
  • H_Donors   0
  • Rotatable_Bonds   3

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