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CS-W001157 4
Total: USD 88.00

4,4,5,5-Tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane

  • CAS No. 865350-17-0

  • Cat. No. CS-0109519
  • Molecule weight166.03
  • Purity95%(stabilized with Phenothiazine)
  • MDL No.MFCD09265121

*For research and further manufacturing use only, not for direct human use.

4,4,5,5-Tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane|CS-0109519

Structure of 865350-17-0

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General Information

  • CAS No. 865350-17-0
  • Cat. No. CS-0109519
  • Purity 95%(stabilized with Phenothiazine)
  • MDL No. MFCD09265121
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₉H₁₅BO₂
  • Molecular Weight 166.03
  • Synonym(s) Allenylboronic Acid Pinacol Ester
  • SMILES C=C=CB1OC(C)(C)C(C)(C)O1

Synthesis

  • Route1
    • In-stock
      2,3-Dimethylbutane-2,3-diol|CS-0015356
      76-09-5
    • null|null
      83816-41-5
    • ~%
    • In-stock
      4,4,5,5-Tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane|CS-0109519
      865350-17-0

    References

    • Tonogaki, Keisuke; Itami, Kenichiro; Yoshida, Jun-Ichi Journal of the American Chemical Society, 2006 , vol. 128, # 5 p. 1464 - 1465
  • Route2
    • In-stock
      2,3-Dimethylbutane-2,3-diol|CS-0015356
      76-09-5
    • null|null
      106-96-7
    • ~54%
    • In-stock
      4,4,5,5-Tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane|CS-0109519
      865350-17-0

    References

    • Bagutski, Viktor; Ros, Abel; Aggarwal, Varinder K. Tetrahedron, 2009 , vol. 65, # 48 p. 9956 - 9960
  • Route3
    • In-stock
      2-(Iodomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane|CS-W005567
      70557-99-2
    • null|null
      4301-14-8
    • ~60%
    • In-stock
      4,4,5,5-Tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane|CS-0109519
      865350-17-0
    • 4,4,5,5-Tetramethyl-2-(prop-2-yn-1-yl)-1,3,2-dioxaborolane|CS-0806138
      1337935-39-3

    References

    • Fandrick, Daniel R.; Saha, Jaideep; Fandrick, Keith R.; Sanyal, Sanjit; Ogikubo, Junichi; Lee, Heewon; Roschangar, Frank; Song, Jinhua J.; Senanayake, Chris H. Organic Letters, 2011 , vol. 13, # 20 p. 5616 - 5619

Safety Information

Download SDS
GHS Pictogram : N/A
GHS No : N/A
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H227
Precautionary Statements : P210-P280-P370+P378-P403+P235-P501

Quality Control

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   1.9589
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   1

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