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CS-W001157 4
Total: USD 88.00

tert-Butyl 16-bromohexadecanoate

  • CAS No. 865200-89-1

  • Cat. No. CS-0514169
  • Purity≥97%
  • MDL No.MFCD31728047
  • HazMat Fee +

    HazMat Fee

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    The shipment is processed through FedEx Ground under the Limited Quantity option.

    Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

    If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

    There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

tert-Butyl 16-bromohexadecanoate|CS-0514169

Structure of 865200-89-1

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Description

tert-Butyl 16-bromohexadecanoate features a long aliphatic chain terminated by a bromo group and a sterically hindered tert-butyl ester. This combination enables controlled functionalization in polymer synthesis and lipid chemistry, where the bromide serves as a reactive handle for cross-coupling while the ester resists hydrolysis under standard conditions.

Application

tert-Butyl 16-bromohexadecanoate serves as a versatile long-chain alkylating agent, enabling efficient C–C bond formation via palladium-catalyzed cross-coupling reactions. The bromide functionality exhibits high reactivity in Suzuki, Stille, and Negishi couplings, while the tert-butyl ester provides bench stability and facilitates straightforward deprotection under mild acidic conditions. Its linear C16 spacer supports applications in lipid-based synthesis and macrocyclic scaffold construction.

General Information

  • CAS No. 865200-89-1
  • Cat. No. CS-0514169
  • Purity ≥97%
  • MDL No. MFCD31728047
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₂₀H₃₉BrO₂
  • Molecular Weight 391.43
  • Synonym(s) None
  • SMILES O=C(OC(C)(C)C)CCCCCCCCCCCCCCCBr

Computational Chemistry Data

  • TPSA   26.3
  • LogP   7.1844
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   15

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362-P405-P501

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