Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate

Name: Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 83400-91-3
Cat. No. CS-0042636
Purity≥97%
MDL No.None

HazMat Fee +

HazMat Fee

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

The shipment is processed through FedEx Ground under the Limited Quantity option.

Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate|CS-0042636

Structure of 83400-91-3

Size

Price

Quantity

* Please select Quantity before adding items.

General Information

CAS No. 83400-91-3
Cat. No. CS-0042636
Purity ≥97%
MDL No. None
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₁₀KO₄
Molecular Weight 185.24
Synonym(s) potassium,2,2-dimethyl-1,3-dioxolane-4-carboxylate
SMILES O=C(O)C1OC(C)(OC1)C.[K]

Description

Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate serves as a stable, bench-ready synthon for constructing complex carbonyl-containing architectures. The cyclic acetal moiety enhances kinetic stability while the carboxylate group enables facile functionalization under mild conditions. This reagent integrates seamlessly into iterative synthesis workflows requiring reliable C–C bond formation.

Application

Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate serves as a stable, bench-ready synthon for the stereoselective introduction of α-alkylated carboxylate units in asymmetric synthesis. Its rigid dioxolane framework enhances diastereoselectivity in nucleophilic additions and functions effectively in transition-metal-catalyzed couplings. The potassium salt ensures excellent solubility and compatibility with standard synthetic protocols, facilitating efficient access to functionalized carbonyl derivatives and complex heterocyclic scaffolds.

Synthesis

Route1
- In-stock
  
  100-79-8
- ~94%
- In-stock
  
  83400-91-3
References
- AUSPEX PHARMACEUTICALS, INC. Patent: US2009/270469 A1, 2009 ; Location in patent: Page/Page column 29-30 ;
Route2
- In-stock
  
  15186-48-8
- ~%
- In-stock
  
  83400-91-3
References
- Bogoslovskii, N. A.; Samokhvalova, N. G.; Isaeva, T. A.; Valashek, I. E.; Filippova, T. M.; Kharchevnikov, A. P. Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 11 p. 2070 - 2081 Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 11 p. 2398 - 2411
Route3
- 82188-74-7
- ~%
- In-stock
  
  83400-91-3
References
- US2006/30574 A1, ; Page/Page column 8 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

To search for quality control of cas , please enter both the product number and the lot/batch number.

Computational Chemistry Data

TPSA 55.76
LogP -0.426
H_Acceptors 3
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Skeleton Aliphatic heterocycle compounds Dioxolane compounds

Key Words

83400-91-3 sigma83400-91-3 manufacturer83400-91-3 price83400-91-3 structure83400-91-3 SDSbuy 83400-91-383400-91-3 supplier83400-91-3 uses83400-91-3 molecular weightprice of 83400-91-383400-91-3 chemical name formula of 83400-91-3

Salutation:	*Country or Region:
*Applicant Name:	*Organization Name:
*Email Address:	Quantity:
CAS NO. :	Product Name:
Remarks:
Upload Pictures

CAS.No.		Product Name
Applicant Name *		Email Address *
Phone Number *		Organization Name*
Country or Region*		Quantity*
Remarks:

Product Name:
Cat. No.: .		CAS NO. :
Quantity:

Potassium 2,2-dimethyl-1,3-dioxolane-4-carboxylate

CAS No. 83400-91-3

Recommended Products

General Information

Description

Application

Synthesis

References

References

References

Safety Information

Quality Control

Computational Chemistry Data

Similar Products

Other Classifications

Recently Viewed Products

Key Words