Lot numbers can be found on the outside label of a product:
Methyl 3-hydroxy-4,5-dimethoxybenzoate
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CAS No. 83011-43-2
- Cat. No. CS-0023808
- Purity≥96%
- MDL No.MFCD00598192
*For research and further manufacturing use only, not for direct human use.
Structure of 83011-43-2
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General Information
- CAS No. 83011-43-2
- Cat. No. CS-0023808
- Purity ≥96%
- MDL No. MFCD00598192
- Storage 4°C, stored under nitrogen
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₁₀H₁₂O₅
- Molecular Weight 212.20
- Synonym(s) None
- SMILES COC1=C(C(O)=CC(C(OC)=O)=C1)OC
Description
Methyl 3-hydroxy-4,5-dimethoxybenzoate features a phenolic hydroxyl group flanked by two methoxy substituents, delivering enhanced solubility and stability in polar solvents. This scaffold integrates readily into complex natural product syntheses and serves as a key intermediate for bioactive aromatic systems requiring controlled polarity and hydrogen-bonding capacity.
Application
Methyl 3-hydroxy-4,5-dimethoxybenzoate serves as a versatile building block in synthetic organic chemistry, enabling the construction of bioactive heterocycles and natural product analogs. Its ortho-hydroxyl group facilitates direct coupling reactions and metal-catalyzed transformations, while the two methoxy substituents enhance solubility and stability. The molecule exhibits excellent bench stability and compatibility with standard protecting group strategies, allowing for sequential functionalization in multi-step syntheses.
Synthesis
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Route1
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67-56-1 -
In-stock
1916-08-1 - ~97%
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In-stock
83011-43-2
References
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Ghinet, Alina; Rigo, Benoit; Henichart, Jean-Pierre; Le Broc-Ryckewaert, Delphine; Pommery, Jean; Pommery, Nicole; Thuru, Xavier; Quesnel, Bruno; Gautret, Philippe Bioorganic and Medicinal Chemistry, 2011 , vol. 19, # 20 p. 6042 - 6054
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Route2
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26409-24-5
- ~97%
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In-stock
83011-43-2
References
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Tanaka, Masahide; Ikeya, Yukinobu; Mitsuhashi, Hiroshi; Maruno, Masao; Wakamatsu, Takeshi Tetrahedron, 1995 , vol. 51, # 43 p. 11703 - 11724
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Route3
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In-stock
1916-08-1
- ~%
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In-stock
83011-43-2
References
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US2002/198195 A1, ;
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 64.99
- LogP 1.196
- H_Acceptors 5
- H_Donors 1
- Rotatable_Bonds 3
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Key Words
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