2,3,6,7,10,11-Hexabromotriphenylene

Name: 2,3,6,7,10,11-Hexabromotriphenylene
Brand: ChemScene
Availability: InStock
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CAS No. 82632-80-2
Cat. No. CS-W011403
Purity≥95%
MDL No.MFCD09834716

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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2,3,6,7,10,11-Hexabromotriphenylene|CS-W011403

Structure of 82632-80-2

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General Information

CAS No. 82632-80-2
Cat. No. CS-W011403
Purity ≥95%
MDL No. MFCD09834716
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₈H₆Br₆
Molecular Weight 701.67
Synonym(s) triphenylene, 2,3,6,7,10,11-hexabromo-
SMILES BrC1=C(Br)C=C2C3=CC(Br)=C(Br)C=C3C4=CC(Br)=C(Br)C=C4C2=C1

Description

2,3,6,7,10,11-Hexabromotriphenylene is a highly brominated polycyclic aromatic compound featuring six bromine atoms positioned at key fusion points across the triphenylene core. This configuration imparts exceptional thermal stability and electronic rigidity, making it ideal for use in advanced materials synthesis, particularly as a building block in conjugated polymers and organic semiconductors where controlled halogenation enables precise post-functionalization.

Application

2,3,6,7,10,11-Hexabromotriphenylene serves as a highly brominated building block for the synthesis of extended π-conjugated materials. Its six bromine substituents enable efficient Pd-catalyzed cross-coupling reactions, facilitating the construction of complex polycyclic architectures with precise regiocontrol. The molecule exhibits excellent bench stability and is well-suited for iterative coupling strategies in the development of advanced organic semiconductors and functionalized carbon nanomaterials.

Synthesis

Route1
- In-stock
  
  217-59-4
- ~92%
- In-stock
  
  82632-80-2
References
- Yatabe, Tetsuo; Harbison, Martha A.; Brand, Johann Diedrich; Wagner, Manfred; Muellen, Klaus; Samori, Paolo; Rabe, Juergen P. Journal of Materials Chemistry, 2000 , vol. 10, # 7 p. 1519 - 1525
Route2
- In-stock
  
  217-59-4
- 7726-95-6
- ~%
- In-stock
  
  82632-80-2
References
- Journal of the American Chemical Society, , vol. 131, p. 7287 - 7292

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 0
LogP 9.7212
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Material Science Material Composite Block Liquid Crystal (LC) Block

Building Blocks Functional Group Bromide

Material Science Covalent Organic Frameworks Halogenated COFs Linkers

Building Blocks Skeleton Aromatic ring compounds phenanthrene compounds

Material Science Material Building Blocks Covalent Organic Frameworks (COFs) Linkers Linkers (Others)

Material Science Polymer/Macromolecule Reagents Covalent Organic Frameworks (COFs) Linkers Linkers (Others)

Material Science Material Building Blocks Liquid Crystal (LC) Building Blocks Triphenylenes

Key Words

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2,3,6,7,10,11-Hexabromotriphenylene

CAS No. 82632-80-2

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