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CS-W001157 4
Total: USD 88.00

1-Bromo-3-(bromomethyl)benzene

  • CAS No. 823-78-9

  • Cat. No. CS-W008571
  • Purity≥98%
  • MDL No.MFCD00000176

*For research and further manufacturing use only, not for direct human use.

1-Bromo-3-(bromomethyl)benzene|CS-W008571

Structure of 823-78-9

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General Information

  • CAS No. 823-78-9
  • Cat. No. CS-W008571
  • Purity ≥98%
  • MDL No. MFCD00000176
  • Storage 4°C
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₇H₆Br₂
  • Molecular Weight 249.93
  • Synonym(s) α,3-Dibromotoluene
  • SMILES BrC1=CC=CC(CBr)=C1

Description

3-Bromobenzyl bromide undergoes reduction with diethylzinc in the presence of Pd(PPh3)4 to yield corresponding hydrocarbon.3-Bromobenzyl bromide was used in the synthesis of:1,7-di(3-bromobenzyl)cyclensubstituted 8-arylquinoline, phosphodiesterase 4 (PDE4) inhibitors

Synthesis

  • Route1
    • null|null
      591-17-3
    • ~79%
    • In-stock
      1-Bromo-3-(bromomethyl)benzene|CS-W008571
      823-78-9

    References

    • Journal of Organic Chemistry, , vol. 79, # 1 p. 223 - 229
  • Route2

    References

    • Organic Process Research and Development, , vol. 6, # 2 p. 190 - 191
  • Route3
    • In-stock
      (3-Bromophenyl)methanol|CS-W007761
      15852-73-0
    • ~%
    • In-stock
      1-Bromo-3-(bromomethyl)benzene|CS-W008571
      823-78-9
    • null|null
      932-77-4

    References

    • Synthesis, , # 24 art. no. P08208SS, p. 3937 - 3940

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS05
Signal Word : Danger
UN#: 3261
Class : 8
Packing Group : Ⅲ
Hazard Statements : H314
Precautionary Statements : P260-P264-P280-P301+P330+P331-P304+P340-P363-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.344
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   1

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