3-Bromo-2-methoxybenzamide

Name: 3-Bromo-2-methoxybenzamide
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CAS No. 791136-88-4
Cat. No. CS-0119842
Purity≥97%
MDL No.None

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FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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General Information

CAS No. 791136-88-4
Cat. No. CS-0119842
Purity ≥97%
MDL No. None
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO₂
Molecular Weight 230.06
Synonym(s) None
SMILES O=C(N)C1=CC=CC(Br)=C1OC

Description

3-Bromo-2-methoxybenzamide features a bromine substituent at the meta position relative to the amide, paired with a methoxy group ortho to the carbonyl. This electron-rich aromatic scaffold enables direct functionalization in cross-coupling reactions and serves as a key intermediate in pharmaceutical synthesis.

Application

3-Bromo-2-methoxybenzamide serves as a versatile building block in medicinal chemistry and materials synthesis, enabling direct functionalization at the aromatic ring via palladium-catalyzed cross-coupling reactions. The bromo group facilitates Suzuki, Stille, and Negishi couplings, while the methoxy substituent offers moderate electron-donating character and ortho-directing influence. Bench-stable and readily purified by column chromatography, it functions efficiently in multi-step syntheses of heterocyclic scaffolds and bioactive molecules.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 52.32
LogP 1.5566
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 2

Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Bromo-2-methoxybenzamide

CAS No. 791136-88-4

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